Magnetic enhancement in cobalt-manganese alloy clusters.

نویسندگان

  • Shuangye Yin
  • Ramiro Moro
  • Xiaoshan Xu
  • Walter A de Heer
چکیده

Magnetic moments of Co(N)Mn(M) and Co(N)V(M) clusters (N < or = 60; M < or = N/3) are measured in molecular beams using the Stern-Gerlach deflection method. Surprisingly, the per atom average moments of Co(N)Mn(M) clusters are found to increase with Mn concentration, in contrast to bulk CoMn. The enhancement with Mn doping is found to be independent of cluster size and composition in the size range studied. Meanwhile, Co(N)V(M) clusters show reduction of average moments with increasing V doping, consistent with what is expected in bulk CoV. The results are discussed within the virtual bound states model.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

An Investigation on Synthesis and Magnetic Properties of Manganese Doped Cobalt Ferrite Silica Core-Shell Nanoparticles for Possible Biological Application

In this work, we investigated synthesis, magnetic properties of silica coated metal ferrite, (CoFe2O4)/SiO2 and Manganese doped cobalt ferrite nanoparticles (MnxCo1-xFe2O4 with x= 0.02, 0.04 and 0.06)/SiO2 for possible biomedical application. All the ferrites nanoparticles were prepared by co-precipitation method using FeCl3.6H2O, CoCl2.6H2O and MnCl2.2H2O as precursors, and were silica coated ...

متن کامل

An Investigation on Synthesis and Magnetic Properties of Manganese Doped Cobalt Ferrite Silica Core-Shell Nanoparticles for Possible Biological Application

In this work, we investigated synthesis, magnetic properties of silica coated metal ferrite, (CoFe2O4)/SiO2 and Manganese doped cobalt ferrite nanoparticles (MnxCo1-xFe2O4 with x= 0.02, 0.04 and 0.06)/SiO2 for possible biomedical application. All the ferrites nanoparticles were prepared by co-precipitation method using FeCl3.6H2O, CoCl2.6H2O and MnCl2.2H2O as precursors, and were silica coated ...

متن کامل

Zinc Alloy Electrodeposition for Corrosion Protection

t is known that the protective value of zinc is partially a result of its ability to form a protective film when plated on a base metal, such as steel. The zinc is sacrificial and corrodes I preferentially to protectthe steel. Although pure zinc coating provides some degree of protection for the substrate, in a severe corrosion environment, zinc is consumed rapidly. For this reason, it is usual...

متن کامل

The effect of carbon distribution on the manganese magnetic moment in bcc Fe-Mn alloy.

First-principles calculations were performed to study the structural, electronic, and magnetic properties of bcc Fe with C impurities alloyed with 2, 3, and 6 at.% of Mn. Our results reveal that both manganese concentration and carbon location with respect to Mn affect the Fe-Mn magnetic interaction. With an increase in Mn concentration in bcc Fe-Mn alloy, the local magnetic moment of manganese...

متن کامل

Investigation on Influences of Synthesis Methods on the Magnetic Properties of Trimetallic Nanoparticles of Iron-Cobalt-Manganese Supported by Magnesium Oxide

Using Fe(NO3)3.9H2O, Co(NO3)2.6H2O and Mn(NO3)2.4H2O the magnetic properties of nanoparticles trimetalic Iron - Cobalt - Manganese, with supported Magnesium oxide have been prepared by Co-precipitation and Solvothermal methods. The prepared samples are characterized by Scanning Electron Micros...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Physical review letters

دوره 98 11  شماره 

صفحات  -

تاریخ انتشار 2007